Isothermal melt and cold crystallization kinetics of poly(aryl ether ketone ether ketone ketone)

Author(s):  
Zhaobin Qiu ◽  
Zhishen Mo ◽  
Hongfang Zhang ◽  
Shouri Sheng ◽  
Caisheng Song
2000 ◽  
Vol 77 (13) ◽  
pp. 2865-2871 ◽  
Author(s):  
Zhaobin Qiu ◽  
Zhishen Mo ◽  
Yingning Yu ◽  
Hongfang Zhang ◽  
Shouri Sheng ◽  
...  

2000 ◽  
Vol 32 (3) ◽  
pp. 287-290 ◽  
Author(s):  
Zhao Bin Qiu ◽  
Hong Wei Zhou ◽  
Zhi Shen Mo ◽  
Hong Fang Zhang ◽  
Zhong Wen Wu

2006 ◽  
Vol 102 (3) ◽  
pp. 2527-2536 ◽  
Author(s):  
Si-Jie Liu ◽  
Xiao-Bo Sun ◽  
Xiang Hou ◽  
Gui-Bin Wang ◽  
Zhen-Hua Jiang

1997 ◽  
Vol 37 (3) ◽  
pp. 568-575 ◽  
Author(s):  
Tianxi Liu ◽  
Zhishen Mo ◽  
Shanger Wang ◽  
Hongfang Zhang

1997 ◽  
Vol 9 (1) ◽  
pp. 1-15 ◽  
Author(s):  
A A Goodwin ◽  
M M Browne

The development of physical aging in four amorphous poly(aryl ether ketone)s at temperatures below the glass transition temperature, Tg, was studied using differential scanning calorimetry (DSC). The change in enthalpy lost on aging, determined by scanning through Tg, was used to determine the kinetics of the aging process through fitting to the Cowie–Ferguson model. The kinetics of aging were found to depend on the ketone–ether ratio as well as the substitution pattern of the polymers. The maximum enthalpy lost at equilibrium, Δ H∞, was found to be a linear function of the change in heat capacity at Tg, Δ Cp(Tg), and the degree of supercooling, Δ T. A composite curve incorporating Tg values from physical aging and dynamic mechanical studies, covering 15 decades, could be fitted to the Volger–Fulcher equation and demonstrated that physical aging is an extension of the glass forming process.


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